This paper develops the notion of relative demicompact elements of an algebra with respect to a Banach subalgebra as a generalization of relative demicompact linear operators acting on Banach spaces. Drawing on this novel notion, we build a new class of Fredholm perturbation regarding a given Banach subalgebra B which contains its inessential ideal k B and the set of left Fredholm perturbations suggested in [6]. The developed class of Fredholm perturbation exhibits that is a two-sided closed ideal of B that is key in the characterization of the weyl spectrum of elements affiliated with B.