In this paper, based on the iteration methods [3,10], we propose a modified multi-step power-inner-outer (MMPIO) iteration method for solving the PageRank problem. In the MMPIO iteration method, we use the multi-step matrix splitting iterations instead of the power method, and combine with the inner-outer iteration [24]. The convergence of the MMPIO iteration method is analyzed in detail, and some comparison results are also given. Several numerical examples are presented to illustrate the effectiveness of the proposed algorithm